Core-scale geophysical and hydromechanical analysis of seabed sediments affected by CO2 venting

Safe offshore Carbon Capture Utilization and Storage (CCUS) includes monitoring of the subseafloor, to identify and assess potential CO2 leaks from the geological reservoir through seal bypass structures. We simulated CO2-leaking through shallow marine sediments of the North Sea, using two gravity core samples from ∼1 and ∼2.1 m below seafloor. Both samples were subjected to brine−CO2 flow-through, with continuous monitoring of their transport, elastic and mechanical properties, using electrical resistivity, permeability, P-wave velocity and attenuation, and axial strains. We used the collected geophysical data to calibrate a resistivity-saturation model based on Archie’s law extended for clay content, and a rock physics for the elastic properties. The P-wave attributes detected the presence of CO2 in the sediment, but failed in providing accurate estimates of the CO2 saturation. Our results estimate porosities of 0.44 and 0.54, a background permeability of ∼10−15 and ∼10-17 m2, and maximum CO2 saturation of 18 % and 10 % (±5 %), for the sandier (shallower) and muddier (deeper) sample, respectively. The finer-grained sample likely suffered some degree of gas-induced fracturing, exhibiting an effective CO2 permeability increase sharper than the coarser-grained sample. Our core-scale multidisciplinary experiment contributes to improve the general interpretation of shallow sub-seafloor gas distribution and migration patterns

Marine dipole–dipole controlled source electromagnetic and coincident-loop transient electromagnetic experiments to detect seafloor massive sulphides: effects of three-dimensional bathymetry

Seafloor massive sulphides (SMSs) are regarded as a potential future resource to satisfy the growing global demand of metals including copper, zinc and gold. Aside from mining and retrieving profitable amounts of massive sulphides from the seafloor, the present challenge is to detect and delineate significant SMS accumulations, which are generally located near mid-ocean ridges and along submarine volcanic arc and backarc spreading centres. Currently, several geophysical technologies are being developed to detect and quantify SMS occurrences that often exhibit measurable contrasts in their physical parameters compared to the surrounding host rock. Here, we use a short, fixed-offset controlled source electromagnetic (CSEM) system and a coincident-loop transient electromagnetic (TEM) system, which in theory allow the detection of SMS in the shallow seafloor due to a significant electrical conductivity contrast to their surroundings. In 2016, CSEM and TEM experiments were carried out at several locations near the Trans-Atlantic Geotraverse hydrothermal field to investigate shallow occurrences of massive sulphides below the seafloor. Measurements were conducted in an area that contains distinct SMS sites located several kilometres off-axis from the Mid-Atlantic ridge, some of which are still connected to hydrothermal activity and others where hydrothermal activity has ceased. Based on the quality of the acquired data, both experiments were operationally successful. However, the data analysis indicates bias caused by three-dimensional (3D) effects of the rough bathymetry in the study area and, thus, data interpretation remains challenging. Therefore, we study the influence of 3D bathymetry for marine CSEM and TEM experiments, focusing on shallow 3D conductors located beneath mound-like structures. We analyse synthetic inversion models for attributes associated with 3D distortions of CSEM and TEM data that are not sufficiently accounted for in conventional 1D (TEM) and 2D (CSEM) interpretation schemes. Before an adequate quantification of SMS in the region is feasible, these 3D effects need to be studied to avoid over/underestimation of SMS using the acquired EM data. The sensitivity of CSEM and TEM to bathymetry is investigated by means of 3D forward modelling, followed by 1D (TEM) and 2D (CSEM) inversion of the synthetic data using realistic error conditions. Subsequently, inversion models of the synthetic 3D data are analysed and compared to models derived from the measured data to illustrate that 3D distortions are evident in the recorded data sets

Marine CSEM synthetic study to assess the detection of CO2 escape and saturation changes within a submarine chimney connected to a CO2 storage site.

Carbon capture and storage (CCS) within sealed geologic formations is an essential strategy to reduce global greenhouse gas emissions, the primary goal of the 2015 United Nations Paris Agreement. Large-scale commercial development of geological CO2 storage requires high-resolution remote sensing methods to monitor CO2 migration during/after injection. A geologic formation containing a CO2 phase in its pore space commonly exhibits higher electrical resistivity than brine-saturated (background) sediments. Here, we explore the added value of the marine controlled-source electromagnetic (CSEM) method as an additional and relevant geophysical tool to monitor moderate to significant changes in CO2 saturation within a fluid conduit breaking through the seal of a CCS injection reservoir, using a suite of synthetic studies. Our 2D CSEM synthetic models simulate various geologic scenarios incorporating the main structural features and stratigraphy of two North Sea sites, the Scanner Pockmark and the Sleipner CCS site. Our results show significant differentiation of leakage through the seal with CO2 saturation (SCO2 ⁠) ranging between 20 and 50 per cent, while our rock physics model predicts that detection below 20 per cent would be challenging for CSEM alone. However, we are able to detect with our 2D inversion models the effects of saturation with 10 and 20 per cent CO2 within a chimney with 10 per cent porosity. We demonstrate that simultaneous inversion of Ey and Ez synthetic electric field data facilitates a sharper delineation of a CO2 saturated chimney structure within the seal, whereas Ez synthetic data present higher sensitivity than Ey to SCO2 variation, demonstrating the importance of acquiring the whole 3D electric field. This study illustrates the value of incorporating CSEM into measurement, monitoring, and verification (MMV) strategies for operating marine CCS sites optimally

Seismic chimney characterisation in the North Sea – Implications for pockmark formation and shallow gas migration

Fluid-escape structures within sedimentary basins permit pressure-driven focused fluid flow through inter-connected faults, fractures and sediment. Seismically-imaged chimneys are recognised as fluid migration pathways which cross-cut overburden stratigraphy, hydraulically connecting deeper strata with the seafloor. However, the geological processes in the sedimentary overburden which control the mechanisms of genesis and temporal evolution require improved understanding. We integrate high resolution 2D and 3D seismic reflection data with sediment core data to characterise a natural, active site of seafloor methane venting in the UK North Sea and Witch Ground Basin, the Scanner pockmark complex. A regional assessment of shallow gas distribution presents direct evidence of active and palaeo-fluid migration pathways which terminate at the seabed pockmarks. We show that these pockmarks are fed from a methane gas reservoir located at 70 metres below the seafloor. We find that the shallow reservoir is a glacial outwash fan, that is laterally sealed by glacial tunnel valleys. Overpressure generation leading to chimney and pockmark genesis is directly controlled by the shallow geological and glaciogenic setting. Once formed, pockmarks act as drainage cells for the underlying gas accumulations. Fluid flow occurs through gas chimneys, comprised of a sub-vertical gas-filled fracture zone. Our findings provide an improved understanding of focused fluid flow and pockmark formation within the sediment overburden, which can be applied to subsurface geohazard assessment and geological storage of CO2

Multiscale characterisation of chimneys/pipes: Fluid escape structures within sedimentary basins

Evaluation of seismic reflection data has identified the presence of fluid escape structures cross-cutting overburden stratigraphy within sedimentary basins globally. Seismically-imaged chimneys/pipes are considered to be possible pathways for fluid flow, which may hydraulically connect deeper strata to the seabed. The properties of fluid migration pathways through the overburden must be constrained to enable secure, long-term subsurface carbon dioxide (CO2) storage. We have investigated a site of natural active fluid escape in the North Sea, the Scanner pockmark complex, to determine the physical characteristics of focused fluid conduits, and how they control fluid flow. Here we show that a multi-scale, multi-disciplinary experimental approach is required for complete characterisation of fluid escape structures. Geophysical techniques are necessary to resolve fracture geometry and subsurface structure (e.g., multi-frequency seismics) and physical parameters of sediments (e.g., controlled source electromagnetics) across a wide range of length scales (m to km). At smaller (mm to cm) scales, sediment cores were sampled directly and their physical and chemical properties assessed using laboratory-based methods. Numerical modelling approaches bridge the resolution gap, though their validity is dependent on calibration and constraint from field and laboratory experimental data. Further, time-lapse seismic and acoustic methods capable of resolving temporal changes are key for determining fluid flux. Future optimisation of experiment resource use may be facilitated by the installation of permanent seabed infrastructure, and replacement of manual data processing with automated workflows. This study can be used to inform measurement, monitoring and verification workflows that will assist policymaking, regulation, and best practice for CO2 subsurface storage operations

Controlled-source electromagnetic data from the TAG hydrothermal field, 26N Mid-Atlantic Ridge

Raw data from electromagnetic survey at the Mid-Atlantic Ridge 26N (JC138, cruise report https://www.bodc.ac.uk/resources/inventories/cruise_inventory/report/16052/ ) , July 2016. Vulcan voltage logger binary files (Constable, S. et al. 2016, Scripps Institution of Oceanography) and DASI electric current transmitter .tdms files (Sinha et al. 1990, University of Southampton) can be read with the Matlab scripts attached (scripts to read Vulcan data are also found at http://marineemlab.ucsd.edu/Projects/lcplot/). Navigation files include CTD measurements at DASI, pressure at each instrument, USBL data for DASI and the end of the array, winch/deep tow cable data, and internal compass readings for the towed Vulcan receivers, some of which are .mat files that can be read with Matlab

CSEM for CO2 Storage – Feasibility Study at Smeaheia to Optimise Acquisition

In this work, we evaluate the use of controlled-source electromagnetics (CSEM) for CO2 monitoring at Smeaheia, a possible candidate for future phases of the Norwegian full-scale CCS project. CSEM is sensitive to electrically resistive material replacing conductive pore water in the pore space, which enables to infer volumetric estimates of the injected CO2 in the formation. CSEM is often used in combination with high-resolution seismic reflection data due to the sensitivity of the two methods to complementary physical properties. Here, we present a technique to optimise the CSEM survey parameters for efficient 4D surveying. Realistic synthetic models prior to and after injection are derived from reservoir modelling and converted to electrical resistivities. Inversion tests are carried out in 2D for the baseline and monitor cases considering realistic data errors. We show that the resistivity changes due to CO2 injection can be monitored using CSEM. We discuss the optimal orientation of the receivers, frequency range and transmitter-receiver offset. We finally discuss a strategy for optimal survey design based on the sensitivity to the CO2 plume.publishedVersio

Model-based identification of the base of the gas hydrate stability zone in multichannel reflection seismic data, offshore Costa Rica

Along the pacific margin offshore Costa Rica the Bottom Simulating Reflector (BSR) shows a patchy occurrence in 2-D seismic reflection profiles. The reason for this can be either lack of free gas beneath parts of the gas hydrate stability zone (GHSZ) or poor seismic imaging. We compare far to near offset stacked common midpoint sections to reduce imaging ambiguity utilizing the amplitude variation with offset effect and thus successfully distinguish BSRs from regular sediment reflections. In combination with 1-D modeling of the base of the GHSZ we disqualify or qualify reflections in the predicted depth range as BSR. Additionally we calculate the heat flow and compare it with an analytical solution to detect thermal anomalies, for example, at the frontal prism. The higher confidence in BSR depths based on the far offset stacks and heat flow calculations allows further analyses on gas hydrate concentration estimates and tectonic evolution of the margin